Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks - Details

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Abstract：

A　rare　3-D　Mn–organic　framework,　[(CH3)2NH2]3[Mn5(btc)4(Ac)(H2O)4]·5H2O　(1),　based　on　pentanuclear　manganese　clusters　as　building　blocks　has　been　prepared　and　structurally　characterized　by　EA,　IR,　TGA,　PXRD,　and　single-crystal　X-ray　diffraction.　Structural　analysis　indicates　the　pentanuclear　manganese　cluster　in　1　has　a　bow-like　configuration,　which　is　the　first　found　to　act　as　secondary　building　unit　in　the　field　of　metal–organic　framework.　Gas　adsorption　measurements　reveal　that　1　can　absorb　a　considerable　amount　of　N2　and　CO2.　©　2016　Informa　UK　Limited,　trading　as　Taylor　&　Francis　Group.

Keyword：

Cluster; Manganese; Metal–organic framework; Pentanuclear

Community：

[ 1 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 2 ] [Li, X.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
[ 3 ] [Wei, K.-Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 4 ] [Zhuang, T.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 5 ] [Xia, W.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 6 ] [Chen, J.-Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 7 ] [Zhang, R.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 8 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
[ 9 ] [Zheng, S.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China

Reprint 's Address：

[Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

stzheng@fzu.edu.cn

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Source ：

Journal of Coordination Chemistry

ISSN： 0095-8972

Year： 2016

Issue： 11-13

Volume： 69

Page： 1792-1801

1 . 7 9 5

JCR@2016

2 . 2 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 2

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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