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author:

Yang, Y. (Yang, Y..) [1] | Wang, T.-T. (Wang, T.-T..) [2] | Zhu, D.-Y. (Zhu, D.-Y..) [3] | Ren, Y.-B. (Ren, Y.-B..) [4]

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Scopus PKU CSCD

Abstract:

The wettability and spreading dynamics of Au-30%Si (mole fraction) alloys on graphite were studied using a modified sessile drop method under vacuum at 1373-1473 K. The results show that the wettability improves with the temperature increasing. The alloy is non-wetting with graphite and final contact angle as large as 100° at 1373 K. When T≥1393 K, the contact angle accelerates apparently with the temperature increasing, and finally presents an excellent wettability with contact angle decreasing to 16°. The formation of interfacial reaction products SiC resulting in the continuous decrease of solid-liquid interfacial energy, which provides the driving force for wetting and spreading. A spreading kinetic model is established, which explains the wetting mechanism from the angle of energy and predicts the solid-liquid interfacial energy decreasing with time in exponential relationship. The experimental results are in accord with the theoretical calculation in reaction-limited spreading. © 2016, Science Press. All right reserved.

Keyword:

Au-Si alloy; Dynamics; Graphite; Wettability

Community:

  • [ 1 ] [Yang, Y.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Wang, T.-T.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Zhu, D.-Y.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Ren, Y.-B.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Zhu, D.-Y.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

Year: 2016

Issue: 6

Volume: 26

Page: 1175-1181

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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