A microporous cobalt-organic framework constructed from mixed tripodal ligands for high CO2 adsorption capacity - Details

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Abstract：

A　novel　three-dimensional　cobalt-organic　framework　[(Me2NH2)Co3(μ3-OH)(tpt)(btb)2]·guest　(1)　(tpt　=　2.4.6-tri(4-pyridinyl)-1,3,5-triazine,　H3btb　=　4.4-,4″-benzene-1,3,5-triyl-tribenzoate)　has　been　obtained　by　employing　mixed　tripodal　ligands　tpt　and　H3btb　under　solvothermal　reaction　condition.　Topological　analysis　reveals　that　the　whole　framework　structure　of　1　possesses　a　two-fold　interpenetrated　3,6-connected　sit　topology.　Remarkably,　the　desolvated　sample　1a　shows　a　high　CO2　uptake　of　89.5　cm3　g-　1　(17.6　wt%)　at　273　K　and　1.0　bar,　which　is　attributed　to　open　metal　sites　and　rich　N　donors　of　1a.　©　2016　Elsevier　B.V.　All　rights　reserved.

Keyword：

CO2 uptake; Microporous metal-organic framework; Mixed ligand; Topology

Community：

[ 1 ] [Zhang, L.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350116, China
[ 2 ] [Zhang, L.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Yang, W.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Wu, X.-Y.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Zhang, G.-H.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 6 ] [Lu, C.-Z.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 7 ] [Chen, W.-Z.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350116, China
[ 8 ] [Chen, W.-Z.]Xiamen University of Technology, Xiamen, Fujian 361024, China

Reprint 's Address：

[Lu, C.-Z.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

czlu@fjirsm.ac.cn

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2016

Volume： 68

Page： 60-62

1 . 6 4

JCR@2016

4 . 4 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 9

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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