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author:

Liu, H. (Liu, H..) [1] | Huang, J. (Huang, J..) [2] | Zhao, D. (Zhao, D..) [3] | Yang, H. (Yang, H..) [4] | Zhang, T. (Zhang, T..) [5]

Indexed by:

Scopus

Abstract:

The electrical property of sealing glass-ceramics is of great importance for Solid Oxide Fuel Cell (SOFC) applications. In spite of their good sintering property, CeO2-containing glass-ceramics often lack in sufficient electrical resistance, due to the formation of CeO2 as a conductive phase. Here we report for the first time that the electrical conductivity of CeO2-containing glass-ceramics can be reduced by an order of magnitude with HfO2 dopant. A mechanism on the improved electrical property has also been proposed in terms of the structural change in HfO2-doped glass-ceramics. In addition, the relationship between phase evolution of HfO2-doped glass-ceramics and the change in conductivity with operational time has been systematically investigated. Moreover, HfO2-doped glass-ceramics show good chemical compatibility with 8 mol.% yttria-stabilized zirconia (8YSZ) electrolyte, after held at 750°C for 500 h. The reported results support the suitability of prepared glass-ceramics as sealing materials for SOFC applications. © 2015 Elsevier Ltd.

Keyword:

Chemical compatibility; Electrical property; Glass-ceramics; Phase evolution; Solid Oxide Fuel Cell

Community:

  • [ 1 ] [Liu, H.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 2 ] [Huang, J.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 3 ] [Zhao, D.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 4 ] [Yang, H.]Department of Materials Science and Engineering, National United University, Miao-Li, 36003, Taiwan
  • [ 5 ] [Zhang, T.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China

Reprint 's Address:

  • [Zhang, T.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Journal of the European Ceramic Society

ISSN: 0955-2219

Year: 2016

Issue: 3

Volume: 36

Page: 917-923

3 . 4 5 4

JCR@2016

5 . 8 0 0

JCR@2023

ESI HC Threshold:324

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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