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author:

Hua, N. (Hua, N..) [1] | Chen, W. (Chen, W..) [2] | Liu, X. (Liu, X..) [3] | Zhang, T. (Zhang, T..) [4]

Indexed by:

Scopus

Abstract:

The non-isothermal and isothermal crystallization kinetics of Zr72.5Al10Fe17.5 glassy alloy was investigated using differential scanning calorimeter (DSC). Under non-isothermal heating condition, the primary phase in the initial crystallization is Zr6Al2Fe phase and the final crystallized products consist of Zr6Al2Fe, Zr2Fe and a-Zr phases. The apparent activation energy for crystallization estimated using the Kissinger method is 342.1 ± 8.1 kJ/mol. The local activation energy decreased with the increase in the crystallization volume fraction during nonisothermal crystallization. Under isothermal heating condition, the average Avrami exponent of about 2.76 implies a mainly diffusion-controlled three-dimensional growth with an increasing nucleation rate. The local activation energy for isothermal crystallization shows a different variation trend from that for nonisothermal crystallization, indicating different nucleation-and-growth mechanisms for the two crystallizaiton conditions. © 2016, Wuhan University of Technology and Springer-Verlag Berlin Heidelberg.

Keyword:

activation energy; avrami exponent; crystallization; glassy alloys

Community:

  • [ 1 ] [Hua, N.]Department of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Hua, N.]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 3 ] [Chen, W.]Department of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Chen, W.]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 5 ] [Liu, X.]Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 6 ] [Zhang, T.]Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, Beijing, 100191, China

Reprint 's Address:

  • [Hua, N.]Department of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Journal Wuhan University of Technology, Materials Science Edition

ISSN: 1000-2413

Year: 2016

Issue: 1

Volume: 31

Page: 191-196

0 . 4 4 7

JCR@2016

1 . 3 0 0

JCR@2023

ESI HC Threshold:324

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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