Rhodium(III)/Amine Synergistically Catalyzed Enantioselective Alkylation of Aldehydes with α,β-Unsaturated 2-Acyl Imidazoles - Details

author：

Gong, J. (Gong, J..) ^[1] | Li, K. (Li, K..) ^[2] | Qurban, S. (Qurban, S..) ^[3] | Kang, Q. (Kang, Q..) ^[4]

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Scopus CSCD

Abstract：

A　synergistic　catalysis　combination　of　chiral-at-metal　rhodium　complex　and　amine　catalyst　was　developed　for　enantioselective　alkylation　of　aldehydes　with　α,β-unsaturated　2-acyl　imidazoles.　The　corresponding　adducts　were　obtained　in　good　yields　with　excellent　enantioselectivities　(up　to　99%　ee).　Copyright　©　2016　SIOC,　CAS,　Shanghai　&　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

alkylation of aldehyde; chiral-at-metal complex; synergistic catalysis

Community：

[ 1 ] [Gong, J.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 2 ] [Li, K.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Qurban, S.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Kang, Q.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Kang, Q.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

kangq@fjirsm.ac.cn

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Source ：

Chinese Journal of Chemistry

ISSN： 1001-604X

Year： 2016

Issue： 12

Volume： 34

Page： 1225-1235

1 . 8 5 2

JCR@2016

5 . 5 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 37

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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