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author:

Huang, K. (Huang, K..) [1] | Lin, L. (Lin, L..) [2] | Yang, K. (Yang, K..) [3] | Dai, W. (Dai, W..) [4] | Chen, X. (Chen, X..) [5] | Fu, X. (Fu, X..) [6]

Indexed by:

Scopus

Abstract:

Pt catalysts supported on TiO2 and CeO2-TiO2 (Pt/TiO2 and Pt/CeO2-TiO2) were prepared by a two-step precipitation-deposition method, respectively. As compared to Pt/TiO2, Pt/CeO2-TiO2 exhibits a higher thermo-catalytic activity and stability for CO+NO reaction, and also exhibits a stronger effect of ultraviolet light (UV) on promoting this reaction. The in-situ FTIR results indicate that the doped CeO2 can significantly improve the adsorption of NO at Pt/CeO2-TiO2, while UV light further enhance the adsorption of NO and its activation. Based on the results of Raman spectrum, electron paramagnetic resonance and the X-ray photoelectron spectroscopy testing, it is proposed that UV irradiation can cause the increase in surface electron density of Pt nanoparticles by the photo-induced electron transfer from TiO2 to Pt. Moreover, the doped CeO2 can further improve the electron transfer from TiO2 to Pt through a process of Ce4+→Ce3+ under UV irradiation, resulting in the adsorption and activation of CO and NO species at Pt/CeO2-TiO2. This result also indicates that the photo-excitation of supports can strengthen the strong interaction between support and metal nanoparticles, and then promote the thermo-catalytic reactivity of catalysts. © 2015 Elsevier B.V.

Keyword:

Carbon monoxide oxidation; Electron transfer; Nitrogen monoxide reduction; Photo-assisted effect; Platinum nanoparticles

Community:

  • [ 1 ] [Huang, K.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Lin, L.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Yang, K.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Dai, W.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Chen, X.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Fu, X.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address:

  • [Dai, W.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou UniversityChina

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2015

Volume: 179

Page: 395-406

8 . 3 2 8

JCR@2015

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 66

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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