A　gold-catalyzed　intermolecular　reaction　of　vinyl　azides　and　ynamides　is　described.　This　process　presents　an　efficient　and　mild　approach　to　multisubstituted　2-aminopyrroles　in　good-to-excellent　yields.　Control　experiments　were　carried　out　to　distinguish　the　reactivity　between　vinyl　azides　and　the　corresponding　2H-azirines.　A　plausible　reaction　mechanism　was　also　proposed　according　to　previous　reports　and　our　preliminary　mechanistic　studies.　©　2015　American　Chemical　Society.