The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers - Details

author：

Yang, X.-D. (Yang, X.-D..) ^[1] | Chen, C. (Chen, C..) ^[2] | Zhang, Y.-J. (Zhang, Y.-J..) ^[3] | Cai, L.-X. (Cai, L.-X..) ^[4] | Zhang, J. (Zhang, J..) ^[5]

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Abstract：

Two　layer-like　coordination　polymers,　{[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1)　and　{[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2),　have　been　solvothermally　synthesized　and　structurally　characterized.　The　two　compounds　own　common　rapid　photochromic　response　but　different　decolorization　behaviors.　The　photoproduct　of　compound　2　is　more　stable　in　air.　The　relationship　between　structure　and　photoresponsive　behavior　has　been　studied　in　detail.　©　2015,　Elsevier　Ltd.　All　rights　reserved.

Keyword：

(6,3) topology; Bipyridinium; Cadmium(II) complex; Decolorization; Photochromism; Single crystal

Community：

[ 1 ] [Yang, X.-D.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Yang, X.-D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Chen, C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Zhang, Y.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Cai, L.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 6 ] [Zhang, J.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 7 ] [Zhang, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Zhang, J.]College of Chemistry, Fuzhou UniversityChina

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2015

Volume： 60

Page： 122-125

1 . 7 6 2

JCR@2015

4 . 4 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：2

CAS Journal Grade：4

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WoS CC Cited Count：

SCOPUS Cited Count： 23

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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