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author:

Li, W. (Li, W..) [1] | Huang, Y. (Huang, Y..) [2] | Tang, D. (Tang, D..) [3] | Zhang, T. (Zhang, T..) [4] | Wang, Y. (Wang, Y..) [5]

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Scopus

Abstract:

In this paper, RuO2-SnO2 binary oxides were prepared using a hydrothermal approach and added to Vulcan XC-72 carbon black as new support material for Pd. The X-ray diffraction, Transmission electron microscopy and X-ray photoelectronic spectra results show that the addition of binary oxides leads to the formation of (Ru,Sn)O2 solid solution in Pd/C catalyst and reduces the particle size of Pd particles due to the anchoring effect. In addition, the electrochemical CO-striping measurement reveals that the Pd/RuO2-SnO2/C catalyst exhibits the largest electrochemical active surface and the best CO tolerance. Moreover, cyclic voltammetry and chronoamperometry tests demonstrate that the Pd/RuO2-SnO2/C catalyst possesses a much higher specific activity (4.4 mA cm-2) than that of the Pd/C catalyst (3.2 mA cm-2) towards ethylene glycol electrooxidation in alkaline media, and better stability as well. These results support the suitability of Pd/RuO2-SnO2/C catalyst developed in this work as a promising candidate for direct alcohol fuel cells (DAFCs) application. ©2015 Elsevier Ltd. All rights reserved.

Keyword:

Composite Support; Direct Alcohol Fuel Cells; Pd Catalysts; Solid Solution

Community:

  • [ 1 ] [Li, W.]College of Materials Science and Engineering, Fuzhou University, Fujian, 350108, China
  • [ 2 ] [Huang, Y.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 3 ] [Tang, D.]College of Materials Science and Engineering, Fuzhou University, Fujian, 350108, China
  • [ 4 ] [Zhang, T.]College of Materials Science and Engineering, Fuzhou University, Fujian, 350108, China
  • [ 5 ] [Wang, Y.]Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address:

  • [Zhang, T.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2015

Volume: 174

Page: 178-184

4 . 8 0 3

JCR@2015

5 . 5 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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