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author:

Fang, L. (Fang, L..) [1] | Zhang, Q. (Zhang, Q..) [2] | Lin, F. (Lin, F..) [3] | Tang, D. (Tang, D..) [4] | Zhang, T. (Zhang, T..) [5]

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Scopus

Abstract:

The insufficient thermal-mechanical stability of sealing interface presents a challenge for the development of solid oxide fuel cells (SOFCs). Here we report for the first time that the presence of gadolinia-doped ceria (GDC) electrolyte leads to the formation of two hardystonite phases, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 and Ca2ZnSi2O7, in the reaction couples between boroaluminosilicate sealing glass-ceramics and GDC powders held at 700°C for 30 days. Similarly, the aggregation of these two hardystonite phases also occurs at the interface between GDC and sealing glass-ceramics under identical heat-treatment. In particular, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 becomes the dominant phase at the sealing interface when the heat-treatment time increases from 7 days to 30 days. Moreover, the sealing interface remains intact after thermal cycles for 100 times, indicating the excellent thermal-mechanical stability of hardystonite phases. Finally, the possible mechanism on the phase evolution of glass-ceramic at the sealing interface has been proposed. © 2015 Elsevier Ltd.

Keyword:

Gadolinia-doped ceria; Phase evolution; Sealing glass-ceramics; Solid oxide fuel cells; Thermal-mechanical stability

Community:

  • [ 1 ] [Fang, L.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 2 ] [Zhang, Q.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 3 ] [Lin, F.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 4 ] [Tang, D.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 5 ] [Zhang, T.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China

Reprint 's Address:

  • [Zhang, T.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Journal of the European Ceramic Society

ISSN: 0955-2219

Year: 2015

Issue: 7

Volume: 35

Page: 2201-2207

2 . 9 3 3

JCR@2015

5 . 8 0 0

JCR@2023

ESI HC Threshold:335

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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