Synthesis of β-Trifluoromethylthio- and β-Trifluoromethylseleno-α,β-unsaturated Ketones through Copper-Mediated Trifluoromethylthio(seleno)lation - Details

author：

Hou, C. (Hou, C..) ^[1] | Lin, X. (Lin, X..) ^[2] | Huang, Y. (Huang, Y..) ^[3] | Chen, Z. (Chen, Z..) ^[4] | Weng, Z. (Weng, Z..) ^[5]

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Abstract：

An　efficient　and　convenient　synthetic　methodology　has　been　developed　with　which　to　construct　β-trifluoromethylthio-　and　seleno-α,β-unsaturated　ketones　through　copper-mediated　trifluoromethylthio(seleno)lation　of　β-bromo　α,β-unsaturated　ketones.　The　corresponding　ketone　products　were　isolated　in　moderate　to　good　yields　and　were　efficiently　converted　into　valuable　alcohols.　©　Georg　Thieme　Verlag.

Keyword：

copper; enones; fluorine; selenium; trifluoromethylthiolation

Community：

[ 1 ] [Hou, C.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Lin, X.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Huang, Y.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Chen, Z.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address：

[Chen, Z.]Department of Chemistry, Fuzhou UniversityChina

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Source ：

Synthesis (Germany)

ISSN： 0039-7881

Year： 2015

Issue： 7

Volume： 47

Page： 969-975

2 . 6 5 2

JCR@2015

2 . 2 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：2

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 39

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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