Flow injection analysis of thiamazole based on strong Ru(bpy)32+ co-reactant electrochemiluminescence - Details

author：

Indexed by：

Scopus

Abstract：

Based　on　the　strong　electrochemiluminescence　(ECL)　reaction　between　thiamazole　and　tris(2,2′-bipyridine)ruthenium(II)　(Ru(bpy)32+),　a　sensitive,　simple　and　rapid　flow　injection　analysis　method　for　the　determination　of　thiamazole　was　developed.　When　a　Pt　working　electrode　was　maintained　at　a　potential　of　+1.50　V　(vs　Ag/AgCl)　in　pH　12.0　H3PO4-NaOH　solution　containing　thiamazole　and　Ru(bpy)32+　at　a　flow　rate　of　1.0　mL/min,　a　linear　range　of　2.0　×　10-7-1.0　×　10-4　mol/L　with　a　detection　limit　of　5.0　×　10-8　mol/L　was　obtained　for　the　detection　of　thiamazole.　The　method　showed　good　reproducibility　with　a　relative　standard　deviation　(RSD)　of　0.75%.　The　method　has　been　successfully　applied　to　the　determination　of　thiamazole　in　spiked　animal　feeds.　In　addition,　a　co-reactant　ECL　mechanism　was　proposed　for　the　thiamazole　-Ru(bpy)32+　system.　Copyright　©　2014　John　Wiley　&　Sons,　Ltd.

Keyword：

Antithyroid; Electrochemiluminescence; Flow injection; Thiamazole

Community：

[ 1 ] [Kong, D.]School of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
[ 2 ] [Kong, D.]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fujian, 350108, China
[ 3 ] [Li, Q.]School of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
[ 4 ] [Jiang, J.]School of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
[ 5 ] [Xinyu, Z.]School of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
[ 6 ] [Xuechou, Z.]School of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
[ 7 ] [Chi, Y.]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fujian, 350108, China
[ 8 ] [Chen, G.]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fujian, 350108, China

Reprint 's Address：

[Chi, Y.]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou UniversityChina

Email：

y.w.chi@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Luminescence

ISSN： 1522-7235

Year： 2015

Issue： 1

Volume： 30

Page： 12-17

1 . 4 5 2

JCR@2015

3 . 2 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：4

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to