Tuning the formations of metal-1,3,5-benzenetricarboxylate frameworks via the assistance of amino acids - Details

author：

Lei, X.-P. (Lei, X.-P..) ^[1] | Lian, T.-T. (Lian, T.-T..) ^[2] | Chen, S.-M. (Chen, S.-M..) ^[3] | Zhang, J. (Zhang, J..) ^[4]

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Scopus

Abstract：

Seven　new　metal-1,3,5-benzenetricarboxylate　coordination　polymers　have　been　synthesized　by　modification　of　auxiliary　components　during　the　assembly　reactions.　Their　structures　have　been　determined　by　single-crystal　X-ray　diffraction　analyses　and　further　characterized　by　XRD　and　TGA.　Interestingly,　they　show　fascinating　topological　structures.　Compounds　1　and　2　possess　the　undulating　layer　structure　with　3-connected　hcb　network　and　(3,6)-connected　kgd　network.　Compound　3　possesses　three-dimensional　(3D)　pillared-layer　structure　with　3-connected　2-fold　interpenetrating　srs　net.　Compound　4　also　has　the　3D　2-fold　interpenetrating　pillared-layer　structure;　however,　it　has　(3,5)-connected　hms　topology　because　the　Cd(II)　center　is　5-connected.　Compound　5　possess　3D　structure　through　hydrogen　bonding　interactions　between　ladder-like　layers.　Compounds　6　and　7　have　the　similar　3D　frameworks　with　4-connected　umc　net　and　(3,7)-connected　(3.4.5)(32.46.55.68)　topology,　respectively.　The　photoluminescent　properties　of　compounds　2-7　were　also　investigated.　©　2014　Elsevier　Inc.　All　rights　reserved.

Keyword：

Coordination polymer; Crystal structure; Metal-organic framework; Topology

Community：

[ 1 ] [Lei, X.-P.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Lian, T.-T.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Chen, S.-M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 4 ] [Chen, S.-M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Zhang, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Chen, S.-M.]College of Chemistry and Chemical Engineering, Fuzhou UniversityChina

Email：

csm@fzu.edu.cn

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Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2015

Volume： 223

Page： 44-52

2 . 2 6 5

JCR@2015

3 . 2 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：2

CAS Journal Grade：3

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WoS CC Cited Count：

SCOPUS Cited Count： 3

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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