Synthesis, structure and luminescent property of a new zinc(II) complex - Details

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Abstract：

One　new　coordination　polymer,　namely　{[Zn(HL)(Hbipy)]2·3H2O}n　(bipy　=　4,4′-　bipyridine,　H4L　=　6-(3′,4′-dicarboxyl-phenoxy)　isophthalic　acid),　has　been　synthesized　through　a　hydrothermal　method　and　characterized　by　single-crystal　X-ray　diffraction,　elemental　analysis,　infrared　spectra　(IR),　and　thermogravimetric　(TG)　analysis.　The　crystal　structure　is　of　monoclinic,　space　group　P21/n　with　a　=　9.6435(3),　b　=　19.8515(7),　c　=　12.9731(5)　Å,　β　=　103.023(4)°,　V　=　2419.67(15)　Å3,　C52H38Zn2N4O21,　Mr　=　1185.6,　Z　=　2,　Dc　=　1.619　g/cm3,　F(000)　=　1200,　μ　=　1.083　mm-1,　the　final　R　=　0.0443　and　wR　=　0.1079　for　4269　observed　reflections　(I　>　2σ(I).　The　compound　features　a　two-dimensional　(2D)　framework　and　stabilizes　itself　by　interlayer　π···π　interactions　and　innerlayer　hydrogen　bonds.　The　2D　layer　presents　a　simple　3-connected　63　topology.　Moreover,　the　thermal　dynamic　stability　and　luminescent　property　of　the　compound　have　also　been　discussed　in　detail.

Keyword：

Coordination polymer; Hydrogen bonds; Interactions; Luminescent property; Topology; π··· π

Community：

[ 1 ] [Zhai, J.-Q.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Zhai, J.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Zhang, Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Zhang, Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Cheng, J.-K.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Yang, J.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 7 ] [Zhang, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 8 ] [Qin, Y.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 9 ] [Yao, Y.-G.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 10 ] [Yao, Y.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

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[Yao, Y.-G.]College of Chemistry, Fuzhou UniversityChina

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Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2015

Issue： 10

Volume： 34

Page： 1513-1518

0 . 5 3 8

JCR@2015

5 . 9 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：4

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SCOPUS Cited Count： 5

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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