α-Trifluoromethylseleno-substituted ketones synthesis via copper-mediated trifluoromethylselenolation of α-bromoketones - Details

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Abstract：

Herein　we　disclose　the　report　on　the　synthesis　of　α-trifluoromethylseleno-substituted　ketone　derivatives　via　copper-mediated　trifluoromethylselenolation　of　α-bromoketones　with　[(bpy)Cu(SeCF3)]2　1.　A　broad　range　of　substituted　2-bromoacetophenone　substrates　were　found　to　react　smoothly　with　1　in　the　presence　of　3　equiv　of　K3PO4　to　afford　the　corresponding　α-trifluoromethylseleno-substituted　ketones　in　good　yields.　A　wide　range　of　functional　groups　were　well　tolerated　and　the　reaction　conditions　are　amenable　to　scale　up.　©　2017　Elsevier　B.V.

Keyword：

Copper; Fluorine; Triﬂuoromethylselenolation; α-Bromoketones

Community：

[ 1 ] [Yang, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 2 ] [Lin, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 3 ] [Zheng, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 4 ] [Lin, G.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 5 ] [Zhang, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 6 ] [You, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China
[ 7 ] [Weng, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityFujian 350108, China

Reprint 's Address：

[You, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

youyi@fzu.edu.cn

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Source ：

Journal of Fluorine Chemistry

ISSN： 0022-1139

Year： 2017

Volume： 204

Page： 1-5

1 . 8 7 9

JCR@2017

1 . 7 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 17

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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