Two new 3D heterometallic chalcogenides based on copper-rich selenogermanate clusters - Details

author：

Wang, Y.-L. (Wang, Y.-L..) ^[1] | Zhang, B. (Zhang, B..) ^[2] | Li, W.-A. (Li, W.-A..) ^[3] | Feng, M.-L. (Feng, M.-L..) ^[4] | Huang, X.-Y. (Huang, X.-Y..) ^[5]

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Scopus

Abstract：

Two　new　three-dimensional　(3D)　copper-rich　selenogermanates　with　organic　amine　cations　as　structural　directing　agents,　namely　(enH2)5[Cu16Ge6Se19(Se2)6]·en　(1)　(en　=　ethylenediamine)　and　[(CH3)2NH2]6[Cu8Ge6Se19]·0.25H2O　(2),　have　been　solvothermally　synthesized　and　structurally　characterized.　Compound　1　is　constructed　by　interconnections　of　icosahedral　[Cu8Se13]　and　octahedral　[Cu4Se6]　clusters　through　bridging　[GeSe3(Se2)]　units　to　form　a　3D　anionic　framework　with　ethylenediamine　cation/molecules　located　in　the　intersecting　channels.　Compound　2　features　a　3D　anionic　framework　constructed　from　[Cu8Se13]　clusters　linked　by　dimeric　[Ge2Se6]　units.　©　2017　Elsevier　B.V.

Keyword：

Copper-rich cluster; Crystal structure; Organic amine; Selenogermanate; Solvothermal synthesis

Community：

[ 1 ] [Wang, Y.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 2 ] [Zhang, B.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Zhang, B.]University of Chinese Academy of Sciences, Beijing, 100049, China
[ 4 ] [Li, W.-A.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Li, W.-A.]College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 7 ] [Huang, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of SciencesChina

Email：

fml@fjirsm.ac.cn

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2017

Volume： 85

Page： 41-44

1 . 8 1

JCR@2017

4 . 4 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：3

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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