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author:

Chen, K. (Chen, K..) [1] | Hou, H. (Hou, H..) [2] | Huang, C. (Huang, C..) [3] | Ji, X. (Ji, X..) [4] | Qiu, X. (Qiu, X..) [5]

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Abstract:

Hierarchical sulfur-doped nitrogenous carbon (S/NC) and nitrogenous carbon (NC) nanosheets are successfully fabricated by carbonization of their corresponding precursor polymers which are synthesized through the polymerization reaction of dianhydride and multi-amine compounds. Hierarchical S/NC nanosheets deliver greatly enhanced reversible capacity, compared with hierarchical NC nanosheets, of 280 mAh g-1 at a current density of 100 mA g-1 after 300 cycles. It is found that the introduction of sulfur species in carbon skeleton results in increasing the turbostratic structures, rather than enlarging the interlayer distances, for boosting the specific capacity of sodium-ion storage. The turbostratic structures and sulfur dopant existed in the carbon can offer more active sites for the sodium-ion storage. Carbon-based materials doped with sulfur are capable of improving the sodium-ion storage property, which can broaden the horizon of designing a string of outstanding carbon materials for the future energy storage technologies. © 2017 IOP Publishing Ltd.

Keyword:

active sites; anode materials; sodium-ion storage; sulfur-doped hard carbon

Community:

  • [ 1 ] [Chen, K.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Chen, K.]College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China
  • [ 3 ] [Hou, H.]College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China
  • [ 4 ] [Huang, C.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Ji, X.]College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China
  • [ 6 ] [Qiu, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Qiu, X.]College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China

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Source :

Nanotechnology

ISSN: 0957-4484

Year: 2017

Issue: 44

Volume: 28

3 . 4 0 4

JCR@2017

2 . 9 0 0

JCR@2023

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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