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author:

Xu, J. (Xu, J..) [1] | Chen, Z. (Chen, Z..) [2] | Zhang, H. (Zhang, H..) [3] | Lin, G. (Lin, G..) [4] | Lin, H. (Lin, H..) [5] | Wang, X. (Wang, X..) [6] | Long, J. (Long, J..) [7]

Indexed by:

Scopus CSCD

Abstract:

For a long time, there has been global concern over the environment and energy problems. Recently, the problems, which have brought about serious effect on the global living condition, have been in the “spotlight” and given impetus to the universal's efforts to head for the same direction: stem the worst warming and strive for the renewable energy source. Hydrogen peroxide (H 2 O 2 ) is undoubtedly a good choice, which holds the promise as a clean, efficient, safe and transferrable energy carrier. Octahedral coordination polymer, Cd 3 (C 3 N 3 S 3 ) 2 , was found to be a robust photocatalyst for H 2 O 2 generation under visible light irradiation. To further improve the H 2 O 2 generation efficiency, adhering the octahedron to reduced graphene (rGO) was applied as the strategy herein. The study shows that by adhering Cd 3 (C 3 N 3 S 3 ) 2 to rGO, the formation of H 2 O 2 is 2.5-fold enhanced and its deformation is concurrently suppressed. This work not only demonstrates the effectiveness of adhering Cd 3 (C 3 N 3 S 3 ) 2 polymer to rGO for the improvement of the polymer's photocatalytic performance, but also proposes a general way for the fabrication of graphene/coordination compound hybrids for maximizing their synergy. © 2017 Science China Press

Keyword:

Cd 3 (C 3 N 3 S 3 ) 2; Coordination polymer; H 2 O 2 generation; Photocatalysis; rGO

Community:

  • [ 1 ] [Xu, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Xu, J.]The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Osaka, 567-0047, Japan
  • [ 3 ] [Chen, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zhang, H.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Lin, G.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Lin, H.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Wang, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Long, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Long, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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Source :

Science Bulletin

ISSN: 2095-9273

Year: 2017

Issue: 9

Volume: 62

Page: 610-618

4 . 1 3 6

JCR@2017

1 8 . 8 0 0

JCR@2023

ESI HC Threshold:297

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 56

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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