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author:

Wang, Z. (Wang, Z..) [1] | Yan, Y. (Yan, Y..) [2] | Chen, Y. (Chen, Y..) [3] | Han, W. (Han, W..) [4] | Liu, M. (Liu, M..) [5] | Zhang, Y. (Zhang, Y..) [6] | Xiong, Y. (Xiong, Y..) [7] | Chen, K. (Chen, K..) [8] | Lv, Z. (Lv, Z..) [9]

Indexed by:

Scopus

Abstract:

Porous metals with a cellular architecture have attracted considerable attention for a diverse range of applications. Extensive efforts have been devoted to exploring cost-effective ways to create porous metals. Here we propose a novel approach for the fabrication of micron porous Ni metals through a redox process in a CH 4 -O 2 gas mixture at 750 °C. The multiple redox cycles at high temperatures facilitate a rapid reconstruction of Ni atoms, producing a cellular architecture. This process is simple and clean, avoiding the use of precious metals and templates. The redox process is applicable to the creation of porous architectures (from surface texturing to 3D cellular structures) on a Ni sheet and a unique hierarchical porous architecture on Ni foam. Furthermore, nanocrystalline MnO 2 is successfully coated on a micron porous Ni foam (MPNF) to form a supercapacitor electrode. The micron porous architectures of the MPNF-MnO 2 electrode enhance not only the electrochemical performance but also the mechanical integrity and robustness, leading to ultrahigh capacitance and excellent cycling stability. More importantly, the strategy of micron-sculpturing of metals using a redox process is readily applicable to other metal systems for the fabrication of cellular metals and alloys for a variety of applications, including catalysis, energy storage and conversion, and chemical sensing. © 2017 The Royal Society of Chemistry.

Keyword:

Community:

  • [ 1 ] [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 2 ] [Wang, Z.]MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, 92 West Dazhi Street, Harbin, 150001, China
  • [ 3 ] [Yan, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 4 ] [Chen, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 5 ] [Han, W.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 6 ] [Liu, M.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 7 ] [Zhang, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 8 ] [Xiong, Y.]MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, 92 West Dazhi Street, Harbin, 150001, China
  • [ 9 ] [Chen, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou Fujian, 350108, China
  • [ 10 ] [Lv, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin Heilongjiang, 150001, China
  • [ 11 ] [Liu, M.]Center for Innovative Fuel Cell and Battery Technologies, School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, N.W., Atlanta, GA 30332, United States

Reprint 's Address:

  • [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, China

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Source :

Journal of Materials Chemistry A

ISSN: 2050-7488

Year: 2017

Issue: 39

Volume: 5

Page: 20709-20719

9 . 9 3 1

JCR@2017

1 0 . 8 0 0

JCR@2023

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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