A novel alb metalloring organic framework with a {Ni12Gd24} cage exhibiting a significant magnetocaloric effect - Details

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author：

Feng, Y.-N. (Feng, Y.-N..) ^[1] | Tian, C.-B. (Tian, C.-B..) ^[2] | Du, S.-W. (Du, S.-W..) ^[3]

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Abstract：

With　the　aid　of　a　bifunctional　6-mercaptonicotinic　acid　ligand,　a　novel　{Ni12Gd24}　cage-based　(6,　12)-c　alb-MROF　that　is　assembled　from　a　{Gd4(OH)4(COO)6}　trigonal-prism　building　unit　and　a　{Ni6S12}　hexagonal-prism　molecular　building　block　has　been　synthesized　for　the　first　time.　It　exhibits　a　large　MCE　value　of　29.86　J　kg-1　K-1　for　ΔH　=　8　T　at　2　K.　©　2017　The　Royal　Society　of　Chemistry.

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Community：

[ 1 ] [Feng, Y.-N.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 2 ] [Feng, Y.-N.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350116, China
[ 3 ] [Tian, C.-B.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 4 ] [Du, S.-W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

Reprint 's Address：

[Tian, C.-B.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

tianchongbin@fjirsm.ac.cn

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Source ：

Dalton Transactions

ISSN： 1477-9226

Year： 2017

Issue： 31

Volume： 46

Page： 10210-10214

4 . 0 9 9

JCR@2017

3 . 5 0 0

JCR@2023

ESI HC Threshold：226

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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