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author:

Lin, Y. (Lin, Y..) [1] | Wu, K.-H.T. (Wu, K.-H.T..) [2] | Yu, L. (Yu, L..) [3] | Heumann, S. (Heumann, S..) [4] | Su, D.S. (Su, D.S..) [5]

Indexed by:

Scopus

Abstract:

Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22 examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, ex situ electrochemical measurements, and ex situ attenuated total reflectance. The zigzag edges of sp 2 carbon planes are shown to play a key role in these reactions. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

Alcohols; carbocatalysis; electrochemistry; oxidation; redox reactions

Community:

  • [ 1 ] [Lin, Y.]Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, China
  • [ 2 ] [Lin, Y.]School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230001, China
  • [ 3 ] [Lin, Y.]Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34–36, Mülheim an der Ruhr, 45470, Germany
  • [ 4 ] [Wu, K.-H.T.]Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, China
  • [ 5 ] [Yu, L.]Research Institute of Photocatalysis, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Heumann, S.]Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34–36, Mülheim an der Ruhr, 45470, Germany
  • [ 7 ] [Su, D.S.]Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, China
  • [ 8 ] [Su, D.S.]Department of Inorganic Chemistry, Fritz Haber Institute of the Max, Planck Society, Faradayweg 4–6, Berlin, 14195, Germany

Reprint 's Address:

  • [Su, D.S.]Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, China

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Source :

ChemSusChem

ISSN: 1864-5631

Year: 2017

Issue: 17

Volume: 10

Page: 3497-3505

7 . 4 1 1

JCR@2017

7 . 5 0 0

JCR@2023

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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