Graphene　is　an　ideal　material　for　the　preparation　of　high　performance　conductive　film　because　of　its　unique　electrical　properties,　excellent　mechanical　ductility　and　good　chemical　stability.　This　paper　presents　the　preparation　of　a　double-layered　graphene/poly(3,　4-ethylenedioxythiophene):　poly(styrenesulfonate)　(PEDOT:PSS)　conductive　film,　in　which　the　PEDOT:PSS　film　was　fabricated　by　using　spray-coating　technique.　The　surface　morphology,　optical　and　electrical　properties　of　the　double-layered　conductive　films　were　investigated.　PEDOT:PSS　can　not　only　reduce　the　surface　resistance　of　the　graphene　films,　but　also　smooth　the　film　surface.　Flexible　organic　light-emitting　diodes　based　on　the　double-layered　film　were　fabricated,　and　the　current　efficiency　increased　with　the　voltage　and　reached　its　maximum　of　0.9　cd/A　when　the　voltage　was　12　V.　The　device　luminance　did　not　show　obvious　degradation　after　100　times　bending　with　a　radius　of　curvature　of　10　mm.　The　hybrid　films　hold　promise　for　the　practical　application　of　FOLEDs.