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author:

Chang, C.-J. (Chang, C.-J..) [1] | Lee, Z. (Lee, Z..) [2] | Wei, M. (Wei, M..) [3] | Chang, C.-C. (Chang, C.-C..) [4]

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Scopus

Abstract:

Magnetic Fe3O4 and NiCo2O4 nanoparticles were used as core materials. The ZnS shell layer is synthesized with zinc acetate and thiourea as precursors by a solvothermal process. NiCo2O4@ZnS and Fe3O4@ZnS core-shell nanoparticles were used as hydrogen production photocatalysts, which can be recycled by magnetic force for repeated hydrogen generation. The morphology, crystalline property, magnetic property, photocatalytic activity, and magnetic separation capability of the core-shell photocatalysts were studied. Fe3O4@ZnS core-shell nanoparticles exhibit better magnetic separation capability than the NiCo2O4@ZnS analog. The optimized photocatalytic hydrogen production rates of NiCo2O4@ZnS and Fe3O4@ZnS core-shell nanoparticles reach 880 μmol h-1 g-1 and 3900 μmol h-1 g- 1, respectively. Both photocatalysts can be recycled by magnetic force. Recycled photocatalysts exhibit good hydrogen generation performance after being recycled for three times. © (2014) by the Committee of WHEC2014.

Keyword:

Core-shell; Fe3O4; H2 production; Magnetic separable; Photocatalyst; ZnS

Community:

  • [ 1 ] [Chang, C.-J.]Department of Chemical Engineering, Feng Chia University, Taichung, Taiwan
  • [ 2 ] [Lee, Z.]Department of Chemical Engineering, Feng Chia University, Taichung, Taiwan
  • [ 3 ] [Wei, M.]Institure of New Energy Technology and Nano-Materials, Fuzhou University, Fuzhou, China
  • [ 4 ] [Chang, C.-C.]Institute of Physics, Academia Sinica, Taipei, Taiwan

Reprint 's Address:

  • [Chang, C.-J.]Department of Chemical Engineering, Feng Chia UniversityTaiwan

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Source :

20th World Hydrogen Energy Conference, WHEC 2014

Year: 2014

Volume: 2

Page: 1297-1304

Language: English

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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