Highly photostable silicon(IV) phthalocyanines containing adamantane moieties: Synthesis, structure, and properties - Details

author：

Shen, X.-M. (Shen, X.-M..) ^[1] | Jiang, X.-J. (Jiang, X.-J..) ^[2] | Huang, C.-C. (Huang, C.-C..) ^[3] | Zhang, H.-H. (Zhang, H.-H..) ^[4] | Huang, J.-D. (Huang, J.-D..) ^[5]

Indexed by：

Scopus

Abstract：

Two　new　axially　disubstituted　silicon(IV)　phthalocyanines　1　and　2　have　been　synthesized　by　treating　silicon　phthalocyanine　dichloride　with　1-adamantanemethanol　or　1-adamamtaneethanol,　respectively.　The　crystal　structure　of　compound　2　has　been　characterized　by　X-ray　diffraction　analysis.　Both　compounds　are　efficient　singlet-oxygen　generator　with　a　quantum　yield　of　0.40-0.43.　With　two　rigid　bulky　adamantane　moieties　at　the　axial　positions,　these　phthalocyanines　not　only　are　essentially　non-aggregated　in　common　solvents,　but　also　exhibit　a　high　photostability.　They　are　about　100　times　more　stable　than　zinc　phthalocyanine　under　the　same　irradiation　conditions.　With　the　goal　of　enhancing　the　biocompatibilities,　interactions　and　conjugations　of　these　two　compounds　with　bovine　serum　albumin　have　also　been　investigated.　©　2010　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Photosensitizer; Photostability; Phthalocyanine; Synthesis

Community：

[ 1 ] [Shen, X.-M.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Jiang, X.-J.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Huang, C.-C.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Zhang, H.-H.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 5 ] [Huang, J.-D.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Huang, J.-D.]State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Email：

jdhuang@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2010

Issue： 46

Volume： 66

Page： 9041-9048

3 . 0 1 1

JCR@2010

2 . 1 0 0

JCR@2023

JCR Journal Grade：1

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 3

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to