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author:

Liu, Z.-Q. (Liu, Z.-Q..) [1] | Zhao, Y.-F. (Zhao, Y.-F..) [2] | Huang, X.H. (Huang, X.H..) [3] (Scholars:黄细河) | Li, H.-H. (Li, H.-H..) [4] (Scholars:李浩宏) | Huang, C.-C. (Huang, C.-C..) [5] (Scholars:黄长沧)

Indexed by:

Scopus CSCD

Abstract:

Two cadmium arsonate coordination polymers, Cd(HL1)2 (1, H2L1 = 4-aminophen-ylarsonatic acid) and Cd(H2L 2)2·2H2O (2, H3L2 = 2-(4-arsonphenylamino)acetic acid), have been synthesized and characterized by IR and single-crystal X-ray diffraction. Crystal data for 1: triclinic, space group P1̄ with a = 5.7559(12), b = 7.0903(14), c = 8.9925(18) Å, α = 89.04(3), β = 80.79(3), y = 85.09(3)°, Dc = 2.496 g·cm-3, μ = 6.095 mm-1, F(000) = 260, Z = 1, the final R = 0.0574 and wR = 0.1376 for 1489 observed reflections with I > 2δ(I). And those for 2: monoclinic, space group P21/c with a = 4.7595(10), b = 9.925(2), c = 22.609(5) Å, β = 91.81(3)°, D c = 2.167 g·cm-3, μ = 4.168 mm-1, F(000) = 684, Z = 2, the final R = 0.0335 and wR = 0.0815 for 2340 observed reflections with I > 2δ(I). The structure of 1 shows a two-dimensional layer consisting of inorganic chains of {CdN2(AsO3) 2} along the a axis linking with the phenyl groups. These layers are further linked through strong interlayer hydrogen bonding interaction to form a three-dimensional hydrogen bond supramolecular architecture. Compound 2 has inorganic chains of {CdO2(AsO3)2} similar to 1, which connect with four adjacent inorganic chains forming a three-dimensional framework.

Keyword:

Arsonates; Cadmium(II); Crystal structure; Syntheses

Community:

  • [ 1 ] [Liu, Z.-Q.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Zhao, Y.-F.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Huang, X.H.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Li, H.-H.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Huang, C.-C.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • 黄长沧

    [Huang, C.-C.]Department of Chemistry, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2010

Issue: 11

Volume: 29

Page: 1724-1730

0 . 6 2 4

JCR@2010

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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