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author:

Zhang, T.-Y. (Zhang, T.-Y..) [1] | Yang, Q.-S. (Yang, Q.-S..) [2] | Shi, H.-X. (Shi, H.-X..) [3] | Han, C. (Han, C..) [4] | Liu, X. (Liu, X..) [5]

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Abstract:

We studied the isothermal adsorption of naphthalene on a viscose-based activated carbon fiber (VACF) in aqueous solution. The adsorption experimental data were fitted to adsorption equations such as the Langmuir, Freundlich, Dubinin-Radushkevitch(D-R), Dubinin-Astalov(D-A), Langmuir-Freundlich(L-F), and Redlich-Peterson (R-P) equations. The effects of temperature, pH, and pre-loaded copper ions on the VACF on the adsorption of naphthalene were investigated. The fitting results show that the micropore volume filling theory fits better than the single-layer adsorption theory for naphthalene adsorption onto VACF. The adsorption of naphthalene occurs spontaneously between 20 and 40 ° C. The adsorption capacity of VACF for naphthalene decreases significantly above 30 ° C. A new mechanism is proposed to explain why the adsorption capacity increases significantly in lower pH aqueous solutions. The reduction of naphthalene takes place on the VACF with pre-loaded copper ions. © Editorial office of Acta Physico-Chimica Sinica.

Keyword:

Activated carbon fiber; Adsorption; Adsorption equation; Copper ion; Naphthalene

Community:

  • [ 1 ] [Zhang, T.-Y.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • [ 2 ] [Zhang, T.-Y.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Yang, Q.-S.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • [ 4 ] [Shi, H.-X.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • [ 5 ] [Han, C.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • [ 6 ] [Liu, X.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Reprint 's Address:

  • [Zhang, T.-Y.]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

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Source :

Acta Physico - Chimica Sinica

ISSN: 1000-6818

Year: 2010

Issue: 2

Volume: 26

Page: 367-372

0 . 7 3 4

JCR@2010

1 0 . 8 0 0

JCR@2023

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 0

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