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author:

Lin, Q. (Lin, Q..) [1] | Li, J. (Li, J..) [2] | Yang, Y. (Yang, Y..) [3] | Xie, Z. (Xie, Z..) [4]

Indexed by:

Scopus

Abstract:

Coal-tar pitch was modified with a bismaleimide (BMI) resin. Rheological properties and carbonization behavior of the pitch-BMI resin composites and optical texture of resultant semi-cokes were studied in this paper. The carbonization behavior was studied by thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy techniques. In addition, the optical texture of resultant semi-cokes was characterized by polarized-light microscopy. Results show that the BMI resin content has great effect on the viscosity of the pitch-BMI resin composites. When the BMI resin content is 40 wt.%, the rheological behavior of the pitch-BMI resin composite is similar to that of a thermosetting resin with a U-type curve. Moreover, the pitch-BMI resin composites have better thermal stability than coal-tar pitch. The addition of BMI resin results in an increase in carbonization yield by 6.5% when the BMI resin content is 40 wt.% of the pitch-BMI resin composite. Also, the BMI resin has great effect on formation of the optical textures. When the BMI resin content is 10 wt.% of the pitch-BMI resin composite, the addition of BMI resin clearly improves the development of anisotropy on carbonization and the optical texture is flow domain anisotropy. Furthermore, there are higher aromaticity and more condensed polynuclear structures in resultant semi-cokes with increasing heat treatment temperature. © 2009 Elsevier B.V. All rights reserved.

Keyword:

Coal-tar pitch; Optical texture; Resin; Thermal behavior

Community:

  • [ 1 ] [Lin, Q.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
  • [ 2 ] [Li, J.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
  • [ 3 ] [Yang, Y.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
  • [ 4 ] [Xie, Z.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China

Reprint 's Address:

  • [Lin, Q.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China

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Source :

Journal of Analytical and Applied Pyrolysis

ISSN: 0165-2370

Year: 2010

Issue: 1

Volume: 87

Page: 29-33

2 . 2 3 4

JCR@2010

5 . 8 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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