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author:

Zhang, S. (Zhang, S..) [1] | Cheng, S. (Cheng, S..) [2]

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Abstract:

Cu-doped tin sulphide (SnS) films with a thickness of about 300nm have been grown on glass substrates by thermal evaporation technique. Different Cu-doped SnS films were obtained by controlling the Cu evaporation time to roughly alter Cu-doping concentration in SnS films (from 5.7 to 23atom). Then they were annealed at a temperature of 250°C and a pressure of 5.0×10 -3Pa for 90min. The structural, optical and electrical properties of the films were characterised by X-ray diffraction, atomic force microscopy, ultraviolet-visible-near infrared spectrometer and Hall-effect measurement system. All the films are polycrystalline SnS with orthorhombic structure, and the crystallites in the films are all exclusively oriented along (111) direction. Annealing can optimise the crystallinity of all the films. With the increase of Cu-doping concentration, the grain size of the films becomes larger and larger, but the roughness decreases. Meanwhile, the evaluated direct bandgap Eg of the SnS:Cu films initially decreases, reaches a minimum value of 1.38eV with 15atom Cu and then increases thereafter. The carrier concentration of the films increases sharply, while the resistivity of the films decreases straightly. All the films are of p-type conductivity. Using the optimised conditions, it is possible to prepare SnS:Cu thin films suitable for absorbers of thin film solar cells. © 2011 The Institution of Engineering and Technology.

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Community:

  • [ 1 ] [Zhang, S.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Zhang, S.]College of Electronics and Information Engineering, Putian University, Putian 351100, China
  • [ 3 ] [Cheng, S.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou 350108, China

Reprint 's Address:

  • [Zhang, S.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou 350108, China

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Source :

Micro and Nano Letters

ISSN: 1750-0443

Year: 2011

Issue: 7

Volume: 6

Page: 559-562

0 . 9 4 4

JCR@2011

0 . 9 7 5

JCR@2018

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 34

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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