Unique (3,12)-Connected Inorganic Lanthanide Cluster Polymer Based on Octahedral Hexanuclear Europium Hydroxide Clusters and Sulfate Anions: Synthesis, Structure, and Luminescence - Details

author：

Sun, Y.-Q. (Sun, Y.-Q..) ^[1] | Mei, H.-X. (Mei, H.-X..) ^[2] | Zhang, H.-H. (Zhang, H.-H..) ^[3] | Chen, Y.-P. (Chen, Y.-P..) ^[4] | Sun, R.-Q. (Sun, R.-Q..) ^[5]

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Abstract：

A　(3,12)-connected　3D　inorganic　luminescent　lanthanide　hydroxide　cluster　polymer　[Eu6(μ6-O)　(μ3-OH)8(H2O)6(SO4)4]n　(1)　has　been　hydrothermally　synthesized　and　characterized.　The　structure　can　be　considered　to　be　constructed　by　linking　12-connected　octahedral　hexanuclear　lanthanide　oxido/hydroxide　clusters　with　3-connected　inorganic　SO42-　anions.　Presently,　it　is　the　first　3D　inorganic　lanthanide　cluster　polymer　based　on　octahedral　hexanuclear　lanthanide　cluster　with　the　highest　connected　binodal　network　topology.　1　displays　red　luminescent　emission　and　exhibits　the　characteristic　transitions　of　the　Eu3+　ion　with　a　decay　lifetime　of　196.25　μs　in　the　solid　state　at　room　temperature.　©　2011　Springer　Science+Business　Media,　LLC.

Keyword：

(3,12)-connected; Hexanuclear lanthanide hydroxide cluster; Lanthanide hydroxide cluster polymer; Sulfate anion

Community：

[ 1 ] [Sun, Y.-Q.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 2 ] [Mei, H.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 3 ] [Zhang, H.-H.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 4 ] [Chen, Y.-P.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 5 ] [Sun, R.-Q.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China

Reprint 's Address：

[Sun, Y.-Q.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China

Email：

sunyq@fzu.edu.cn

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Source ：

Journal of Cluster Science

ISSN： 1040-7278

Year： 2011

Issue： 2

Volume： 22

Page： 279-288

0 . 9 1 6

JCR@2011

2 . 7 0 0

JCR@2023

JCR Journal Grade：3

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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