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author:

Cai, G. (Cai, G..) [1] (Scholars:蔡国辉) | Hong, H. (Hong, H..) [2] | Wang, L. (Wang, L..) [3] | Lan, R. (Lan, R..) [4] | Zheng, Y. (Zheng, Y..) [5] | Wei, K. (Wei, K..) [6]

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Scopus PKU CSCD

Abstract:

SBA-15 and Ce-SBA-15 molecular sieves were synthesized by microwave assistant sol-gel method with nonionic triblock co-polymer surfactant P123 as the template and tetraethyl orthosilicate as the silicon source, and were characterized by means of XRD, XPS and UV-Vis DRS. The results showed that ordered degree of Ce-SBA-15 molecular sieves was higher than that of SBA-15 molecular sieves and the cerium species existed in the forms of both Ce4+ and Ce3+. With CO oxidation as the model reaction, the influences of Ni promoter on the catalytic performances of the Pt-based catalysts supported on both the synthesized molecular sieves were investigated. The results showed that the activity of Pt/Ce-SBA-15 was better than that of Pt/SBA-15, and adding the Ni promoter further enhanced the catalyst activity. The complete oxidation of CO was realized at 160°C over Pt-Ni/Ce-SBA-15 catalyst. To reach the same conversion, the reaction temperature has to be at 245°C in the case of Pt/SBA-15.

Keyword:

Carbon monoxide oxidation reaction; Cerium; Nickel promoter; Platinum catalyst; SBA-15 molecular sieve

Community:

  • [ 1 ] [Cai, G.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou Fujian 350002, China
  • [ 2 ] [Hong, H.]School of Chemistry and Materials Science, Fujian Normal University, Fuzhou Fujian 350007, China
  • [ 3 ] [Wang, L.]School of Chemistry and Materials Science, Fujian Normal University, Fuzhou Fujian 350007, China
  • [ 4 ] [Lan, R.]School of Chemistry and Materials Science, Fujian Normal University, Fuzhou Fujian 350007, China
  • [ 5 ] [Zheng, Y.]School of Chemistry and Materials Science, Fujian Normal University, Fuzhou Fujian 350007, China
  • [ 6 ] [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou Fujian 350002, China

Reprint 's Address:

  • 魏可镁

    [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou Fujian 350002, China

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Source :

Petrochemical Technology

ISSN: 1000-8144

CN: 11-2361/TQ

Year: 2011

Issue: 6

Volume: 40

Page: 585-589

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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