Synthesis of the first 1,3-disubstituted 1,3-butadienyl heteroannular bridged [4]ferrocenophane - Details

author：

Wu, K.-Q. (Wu, K.-Q..) ^[1] | Xie, L.-L. (Xie, L.-L..) ^[2] | Zhang, Y.-F. (Zhang, Y.-F..) ^[3] | Xu, F.-B. (Xu, F.-B..) ^[4] | Yuan, Y.-F. (Yuan, Y.-F..) ^[5]

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Scopus

Abstract：

An　unusual　heteroannular　cyclization　of　methyl　4-(((1′-　(trimethylsilyl)ethynyl)ferrocenyl)ethynyl)benzoate　(11)　under　the　basic　desilylation　condition　yielded　1,1′-(l-methoxy-3-(4′-　(methoxycarbonyl)phenyl)-1,3-butadienylene)ferrocene　(7),　the　first　reported　1,3-disubstituted　1,3-butadienyl　heteroannular　bridged　[4]ferrocenophane.　Compound　7　has　been　characterized　by　elemental　analysis,　IR　spectra,　1H　NMR　spectroscopy　and　X-ray　diffraction　analysis.　The　electrochemical　behavior　has　been　investigated　by　cyclic　voltammetry.　The　DFT　calculation　results　of　7　are　also　reported.　©　2010　Elsevier　B.V.　All　rights　reserved.

Keyword：

[4]Ferrocenophane; Alkynylferrocene; Desilylation; Heteroannular cyclization

Community：

[ 1 ] [Wu, K.-Q.]Department of Chemistry, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
[ 2 ] [Xie, L.-L.]Department of Chemistry, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
[ 3 ] [Zhang, Y.-F.]Department of Chemistry, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
[ 4 ] [Xu, F.-B.]State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
[ 5 ] [Yuan, Y.-F.]Department of Chemistry, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China
[ 6 ] [Yuan, Y.-F.]State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
[ 7 ] [Yuan, Y.-F.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Yuan, Y.-F.]Department of Chemistry, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou, Fujian 350108, China

Email：

yaofeng_yuan@fzu.edu.cn

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Source ：

Journal of Organometallic Chemistry

ISSN： 0022-328X

Year： 2011

Issue： 8

Volume： 696

Page： 1491-1495

2 . 3 8 4

JCR@2011

2 . 1 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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