An organic-inorganic hybrid heterobridging luminescent copper(i) polymer exhibiting thermochromic behavior - Details

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Abstract：

A　3-D　organic-inorganic　hybrid　heterobridging　copper(i)　polymer　{[Cu　2I2(Hgtsc)]·2DMF}n　(1A)　(Hgtsc=glyoxal-dithiosemicarbazone)　with　an　unusual　bridging　mode　involving　iodine　and　sulfur　atoms　has　been　structurally　determined,　which　was　constructed　from　supramolecular　interactions　between　2-D　hybrid　layers　[Cu2I　2(Hgtsc)]n　and　solvent　molecules　(DMF).　Strong　luminescence　can　be　detected　and　interestingly,　thermochromic　behavior　can　be　observed.　©　2011　The　Royal　Society　of　Chemistry.

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[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Wang, Y.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Dong, H.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 5 ] [Wu, Y.-L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Wang, M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 7 ] [Huang, S.-W.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

zrchen@fzu.edu.cn

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Source ：

CrystEngComm

ISSN： 1466-8033

Year： 2011

Issue： 6

Volume： 13

Page： 1778-1781

3 . 8 4 2

JCR@2011

2 . 6 0 0

JCR@2023

JCR Journal Grade：1

CAS Journal Grade：2

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SCOPUS Cited Count： 15

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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