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author:

Ni, J. (Ni, J..) [1] | Wang, R. (Wang, R..) [2] | Kong, F. (Kong, F..) [3] | Zhang, T. (Zhang, T..) [4] | Lin, J. (Lin, J..) [5] | Lin, B. (Lin, B..) [6] | Wei, K. (Wei, K..) [7]

Indexed by:

Scopus PKU CSCD

Abstract:

The effect of alkaline-earth oxides as promoters on Ru/AC (AC = activated carbon) catalysts was explored. Alkaline-earth metal oxides can reduce the agglomeration of ruthenium particles at high temperatures, which increases the amount of available ruthenium. The influence of the Mg promoter on the distribution and activity of the Ru/AC catalyst were investigated by CO chemisorption, X-ray diffraction, and energy dispersive spectrometry and by an activity test for ammonia synthesis. The results show that a specific quantity of magnesium significantly promotes the uniform distribution of Ba and Ru on the surface of AC, which enhances catalytic activity. The introduction of Mg significantly improved the size of the Ru particles and increased the Ru surface area. The distribution and interaction were improved greatly for the Ba promoter and the Ru precursor on the surface of the AC because of the addition of the Mg promoter. The introduction of magnesium to Ru-Ba-K/AC significantly improved the utilization ratio of the noble metals and the performance-price ratio.

Keyword:

Activated carbon; Ammonia synthesis; Barium; Magnesium; Ruthenium

Community:

  • [ 1 ] [Ni, J.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wang, R.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Kong, F.]Petrochemical Research Institute of Petrochina Company Limited, Beijing 100029, China
  • [ 4 ] [Zhang, T.]Petrochemical Research Institute of Petrochina Company Limited, Beijing 100029, China
  • [ 5 ] [Lin, J.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Lin, B.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China
  • [ 7 ] [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Ni, J.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China

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Source :

Chinese Journal of Catalysis

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2011

Issue: 3

Volume: 32

Page: 436-439

1 . 1 7 1

JCR@2011

1 5 . 7 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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