A glycine ligand coordinated hybrid complex constructed from hexanuclear copper clusters and octamolybdates - Details

author：

Jiang, X.-Y. (Jiang, X.-Y..) ^[1] | Wu, X.-Y. (Wu, X.-Y..) ^[2] | Yu, R.-M. (Yu, R.-M..) ^[3] | Yuan, D.-Q. (Yuan, D.-Q..) ^[4] | Chen, W.-Z. (Chen, W.-Z..) ^[5]

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Abstract：

Self-assembly　of　the　sodium　molybdate,　copper　chloride　and　glycine　in　aqueous　solution　results　in　a　novel　compound,　{[NaCu6(Gly)　8(H2O)2][Mo8O26(GlyH)　2(Cu(Gly)H2O)]2}{NaCu6(Gly)　8(H2O)2}{Mo8O26(GlyH)　2}•16H2O　(1).　Compound　1　contains　a　new　unit　of　{[NaCu6(Gly)8(H2O)2][Mo　8O26Cu(Gly)2]2},　in　which　the　[Mo8O26Cu(Gly)2]　polyoxometalate　units　are　connected　by　the　[NaCu6(Gly)8(H2O)2]　hexanuclear　copper　cluster.　The　magnetic　measurement　of　1　shows　that　ferromagnetic　coupling　exists　between　the　magnetic　centers　of　the　hexanuclear　copper　cluster.　©　2011　Elsevier　B.V.　All　rights　reserved.

Keyword：

Amino acid; Hexanuclear copper cluster; Hybrid material; Magnetic properties; Polyoxometalate

Community：

[ 1 ] [Jiang, X.-Y.]College of Materials Science and Engineering, Fuzhou University, Fujian 350108, China
[ 2 ] [Jiang, X.-Y.]Fujian University of Technology, Fuzhou, Fujian 350108, China
[ 3 ] [Wu, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Yu, R.-M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Yuan, D.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 6 ] [Chen, W.-Z.]Fujian University of Technology, Fuzhou, Fujian 350108, China

Reprint 's Address：

[Jiang, X.-Y.]College of Materials Science and Engineering, Fuzhou University, Fujian 350108, China

Email：

xyjiang@fjut.edu.cn

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2011

Issue： 9

Volume： 14

Page： 1546-1549

1 . 9 7 2

JCR@2011

4 . 4 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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