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author:

Fan, Q. (Fan, Q..) [1] | Yu, C. (Yu, C..) [2] | Cao, F. (Cao, F..) [3] | Chen, J. (Chen, J..) [4] | Wei, L. (Wei, L..) [5]

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Scopus CSCD

Abstract:

BiOBr nanoplates with high crystallinity were first synthesized. Then, Pd nanoparticles with different contents were deposited over BiOBr via photochemical vapor deposition (PCVD) method. The prepared products were characterized by N2-physical adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), photoluminescence emission (PL) spectroscopy, and UV-Vis diffuse reflectance spectroscopy (DRS). The effects of Pd concentration on light absorption and photocatalytic activity of BiOBr in degradation of acid orange II were evaluated under both UV light (λ = 254 nm) and visible light irradiation. The N2-physical adsorption test shows that the presence of Pd nanoparticles could not obviously change the specific surface area of the catalyst. The UV-Vis DRS results indicate that Pd nanoparticles could slightly shift the light absorption edge of BiOBr to long wavelength direction. PL spectra suggested that Pd could suppress the recombination of photogenerated hole-electron pairs. Under UV light irradiation, Pd 0.5% (mass fraction) with loading can increase the photocatalytic activity of BiOBr by 60%, while under visible light irradiation, 4% is found to be the optimum content of Pd, which results in an increase of 50% in photocatalytic activity.

Keyword:

Acid orange II; BiOBr; Pd nanoparticles; Photocatalysis

Community:

  • [ 1 ] [Fan, Q.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • [ 2 ] [Yu, C.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • [ 3 ] [Yu, C.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Cao, F.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • [ 5 ] [Chen, J.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • [ 6 ] [Wei, L.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

Reprint 's Address:

  • 余长林

    [Yu, C.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

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Source :

Nanotechnology and Precision Engineering

ISSN: 1672-6030

CN: 12-1458/O3

Year: 2013

Issue: 6

Volume: 11

Page: 524-528

3 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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