• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Yu, C. (Yu, C..) [1] | Cao, F. (Cao, F..) [2] | Li, G. (Li, G..) [3] | Wei, R. (Wei, R..) [4] | Yu, J.C. (Yu, J.C..) [5] | Jin, R. (Jin, R..) [6] | Fan, Q. (Fan, Q..) [7] | Wang, C. (Wang, C..) [8]

Indexed by:

Scopus

Abstract:

Novel noble metal (Rh, Pd, Pt)/BiOX(Cl, Br, I) composite photocatalysts were prepared and well characterized by nitrogen-physical adsorption, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectra (DRS), X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) emission spectroscopy. The effects of noble metals deposition on the optical and photocatalytic performance of BiOX in degradation of the acid orange II dye under both UV and visible light irradiation were systematically investigated. Results show that noble metal depositions enhance their visible light absorption and photocatalytic performance. However, catalytic activity is controlled by the species and concentration of noble metal. Over BiOCl, the noble metals, abilities to promote activity are in the orders Pt > Pd > Rh and Rh > Pt > Pd under UV light and visible light irradiation, respectively. Over different BiOX with optimal noble metal content, the best UV light activities are in the order Pd(0.5%)/BiOBr > Pt(1%)/BiOCl > Pd(2%)/BiOCl. Under visible light illumination, the best activities change to Pd(4%)/BiOBr > Pd(0.5%)/BiOI > Rh(1%)/BiOCl. The enhanced photocatalytic efficiency could be attributed to the promoted separation rate of photo-generated e -/h+ pairs and the role of plasmon photocatalysis caused by deposited noble metal nanoparticles. © 2013 Elsevier B.V. All rights reserved.

Keyword:

Bismuth oxyhalide; Enhanced mechanism; Noble metal nanoparticle; Photocatalysis; Plasmon photocatalysis

Community:

  • [ 1 ] [Yu, C.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China
  • [ 2 ] [Yu, C.]Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States
  • [ 3 ] [Cao, F.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China
  • [ 4 ] [Cao, F.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Li, G.]Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States
  • [ 6 ] [Wei, R.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China
  • [ 7 ] [Yu, J.C.]Department of Chemistry, Center of Novel Functional Molecules, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
  • [ 8 ] [Jin, R.]Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States
  • [ 9 ] [Fan, Q.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China
  • [ 10 ] [Wang, C.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China

Reprint 's Address:

  • [Yu, C.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou 341000, Jiangxi, China

Show more details

Related Keywords:

Related Article:

Source :

Separation and Purification Technology

ISSN: 1383-5866

Year: 2013

Volume: 120

Page: 110-122

3 . 0 6 5

JCR@2013

8 . 2 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:222/10052091
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1