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author:

Chen, L. (Chen, L..) [1] | Liu, J.-D. (Liu, J.-D..) [2] | Zhang, S.-Q. (Zhang, S.-Q..) [3]

Indexed by:

Scopus PKU CSCD

Abstract:

With the aim to obtain high performance cathode materials for lithium-sulfur batteries, composite of mesoporous carbon (MC) loaded with ZnS (ZnS/MC) was prepared through ultrasonic dispersion and heat treatment. The as-prepared composite was blended with elemental sulfur by heating, then cathode materials (ZnS/MC/S) was obtained. The ZnS/MC composite was characterized by XRD, SEM, EDS and N2 adsorption-desorption isotherms. The results showed that ZnS particle was uniformly loaded to the surface of MC through ultrasonic dispersion when content of ZnS was less than 17wt%. ZnS nanoparticles aggregated to form sphalerite ZnS by heat treatment or increasing content of ZnS. Cyclic voltammetry test showed that ZnS accelerated the oxidation process of polysulfides. Charge/discharge tests indicated that the initial discharge specific capacity was 1354.6 mAh/g, while the coulombic efficiency of the first charge and discharge was 98.7%. The capacity still remained 650 mAh/g after 50 cycles.

Keyword:

Cyclic performance; Lithium sulfur battery; Mesoporous carbon; Ultrasonic dispersion; ZnS

Community:

  • [ 1 ] [Chen, L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Liu, J.-D.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Zhang, S.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

Reprint 's Address:

  • [Liu, J.-D.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

Journal of Inorganic Materials

ISSN: 1000-324X

Year: 2013

Issue: 10

Volume: 28

Page: 1127-1131

0 . 5 3 7

JCR@2013

1 . 7 0 0

JCR@2023

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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