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author:

Yan, T. (Yan, T..) [1] | Zhang, H. (Zhang, H..) [2] | Luo, Q. (Luo, Q..) [3] | Ma, Y. (Ma, Y..) [4] | Lin, H. (Lin, H..) [5] | You, J. (You, J..) [6]

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Scopus

Abstract:

Plasmonic photocatalysts Ag/AgBr composites were synthesized by a facile one-step solvothermal route. Unlike the traditional photoreduction method, metallic Ag in the present work was in situ anchored on the surface of AgBr by reducing radicals created through the thermal process. The structures (e.g., particle size, composition, and dispersion) of metallic Ag nanoparticles could be well controlled by simply changing the reaction temperature and solvent. The as-prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and diffuse reflectance spectra (DRS). The as-prepared Ag/AgBr composites exhibited excellent photocatalytic efficiency for the degradation of azo dye methyl orange (MO), phenol, and 2-chlorophenol under visible light irradiation. It was found that the activity was highly dependent on the particle size, composition and the dispersing extent of Ag nanoparticles. The photocatalytic mechanism was studied by radical-trapping experiments and the photoluminescence (PL) technique with terephthalic acid, and the results indicated that O2- and h+ played great roles in the rapid degradation of organic pollutants under visible light irradiation. © 2013 Elsevier B.V.

Keyword:

Controllable synthesis; One-pot; Plasmonic Ag/AgBr; Solvothermal route

Community:

  • [ 1 ] [Yan, T.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
  • [ 2 ] [Zhang, H.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
  • [ 3 ] [Luo, Q.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
  • [ 4 ] [Ma, Y.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
  • [ 5 ] [Lin, H.]Fujian Provincial Key Lab. of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [You, J.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China

Reprint 's Address:

  • [Yan, T.]Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2013

Volume: 232

Page: 564-572

4 . 0 5 8

JCR@2013

1 3 . 4 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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