Synthesis crystal structure and properties of iodide, hexafluorophosphate and bis(trifluoromethane sulfonamide) salts of 1-ferrocenyl methyl-2-ferrocenyl-3-alklybenzimidazolium - Details

author：

Indexed by：

Scopus PKU CSCD

Abstract：

1-Ferrocenly　methyl-2-ferrocenly　benzimidazole　was　sythesized　by　the　reaction　of　o-phenylenediamine　with　ferrocenecarboxaldehyde　in　the　condition　of　toluenesulfonic　acid　as　catalyst.　Iodized　salts　(3,　4)　of　1-ferrocenyl　methyl-　2-ferrocenyl-3-alkylbenzimidazolium　were　formed　by　the　reaction　of　compound　2　with　alkyl　iodide.　Hexafluorophosphate　salts　(5,　6)　and　bis(trifluoromethane　sulfonimide)　salts　(7,　8)　of　1-ferrocenyl　methyl-2-ferrocenyl-3-alkylbenzimidazolium　were　obtained　by　the　anion　exchange　reaction　of　compounds　3　and　4.　All　of　these　salts　were　characterized　by　1H　NMR,　13C　NMR,　IR,　MS,　HRMS　and　elemental　analysis.　In　the　crystal　of　compound　5,　the　compound　was　assembled　to　a　chain　supramolecular　structure　along　axis　c　by　the　intermolecular　hydrogen　bonds.　Electrochemical　analysis　demonstrated　that　the　quasi-reversible　oxidation　waves　split　double　of　Fe　in　ferrocene　fragment　of　compounds　3~8;　UV-Vis　absorption　spectra　show　that　these　salts　possess　photoinduced　charge　migration　phenomenon.　And　the　iodized　salts　presented　good　catalytic　effect　on　decomposition　of　ammonium　perchlorate　(AP)　in　DSC-TG　test.　©　2013　Chinese　Chemical　Society　and　SIOC,　CAS.

Keyword：

Ammonium perchlorate; Benzimidazolium; Crystal structure; Ferrocene; Thermal decomposition

Community：

[ 1 ] [Ye, H.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 2 ] [Ye, H.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 3 ] [Wang, W.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 4 ] [Wang, W.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 5 ] [Zhu, X.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 6 ] [Zhu, X.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 7 ] [Chen, W.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 8 ] [Chen, W.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 9 ] [Xie, L.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 10 ] [Xie, L.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 11 ] [Yuan, Y.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China
[ 12 ] [Yuan, Y.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China

Reprint 's Address：

[Xie, L.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350108, China

Email：

xielili@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Chinese Journal of Organic Chemistry

ISSN： 0253-2786

Year： 2013

Issue： 4

Volume： 33

Page： 827-834

0 . 8 5 8

JCR@2013

1 . 8 0 0

JCR@2023

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to