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author:

Li, W. (Li, W..) [1] | Yuan, Y.-F. (Yuan, Y.-F..) [2] | Li, X.-L. (Li, X.-L..) [3] | Su, X.-L. (Su, X.-L..) [4] | Sun, W.-H. (Sun, W.-H..) [5]

Indexed by:

Scopus

Abstract:

In order to investigate a noise-like signal appearing in dynamic mode measurement during laser flash photolysis experiments, five compounds were chosen which show this abnormal phenomenon. The reproducibility of this phenomenon was done repeatedly, indicating that it originates from each molecular structural property. Also their two regulation pattern or features were found by our analysis. One is a U-shaped curve of main frequency intensity with time and it seems to be directly related to the concentration of the T 1 excited state. The other is a high damping oscillation curve of the frequency shift with time and this curve seems to be indicating an energy transportation process from light into chemical energy. Finally, a possible origin of hydrogen nuclear optical resonance was proposed for the abnormal signal. © 2012 Elsevier B.V. All rights reserved.

Keyword:

Electronic triplet state; Laser flash photolysis; Nuclear spin; Transient absorption signal

Community:

  • [ 1 ] [Li, W.]Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • [ 2 ] [Yuan, Y.-F.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 3 ] [Li, X.-L.]Institute of Ferrous Metallurgy, RWTH Aachen, Aachen, Germany
  • [ 4 ] [Su, X.-L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 5 ] [Sun, W.-H.]Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Reprint 's Address:

  • [Li, W.]Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

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Source :

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ISSN: 1386-1425

Year: 2013

Volume: 105

Page: 569-576

2 . 1 2 9

JCR@2013

4 . 3 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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