A new heterometallic hybrid based on polymeric iodoplumbate and lanthanide metal-carboxylic coordination polycation - Details

author：

Indexed by：

Scopus

Abstract：

A　3-D　supramolecular　hybrid　{[La(EPC)3(H2O)　3]2(Pb6I18)}n　(EPC　+　=　N-ethyl-pyridium-4-carboxylate)　(1)　has　been　structurally　determined,　which　assume　significance　for　its　incorporating　lanthanide　metal-carboxylic　coordination　polycation　into　polymeric　iodoplumbate　to　get　heterometallics.　1　consists　of　1-D　(Pb6I18)n6n-　zigzag-like　anion　chains　with　lanthanide　metalcarboxylic　[La(EPC)　3(H2O)3]n3n+　polycations,　which　arrange　in　a　criss-cross　configuration.　C-H⋯I　and　C-H⋯O　hydrogen　bonds　among　inorganic　anions　and　polycations　contribute　to　the　formation　of　a　3-D　supramolecular　framework.　Moreover,　the　framework　displays　an　absorption　edge　at　2.46　eV　which　is　comparable　to　PbI2＇s　absorption　edge.　©　2012　Elsevier　B.V.　All　rights　reserved.

Keyword：

Hybrid framework; Optical adsorption; Polymeric iodoplumbate

Community：

[ 1 ] [Gong, A.-W.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Wu, H.-Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Lian, Z.-X.]School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China
[ 4 ] [Dong, H.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 5 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 6 ] [Li, H.-H.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 7 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 8 ] [Chen, Z.-R.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Email：

lihh@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Journal of Molecular Structure

ISSN： 0022-2860

Year： 2013

Volume： 1035

Page： 109-113

1 . 5 9 9

JCR@2013

4 . 0 0 0

JCR@2023

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to