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author:

Jiang, L. (Jiang, L..) [1] | Wang, Y. (Wang, Y..) [2] | Wang, X. (Wang, X..) [3] | Luo, Y. (Luo, Y..) [4] | Cao, Y. (Cao, Y..) [5] | Wei, K. (Wei, K..) [6]

Indexed by:

Scopus CSCD

Abstract:

High thermally stable mesoporous alumina doped with lanthanum was synthesized using inorganic nitrates as precursors and employing pluronic P123 (P123, (EO20PO70EO20, EO=ethylene oxide, PO=propylene oxide)) as a structure-directing agent. After calcination at 400 C, the resultant lanthanum doped alumina exhibited a γ-Al2O 3 phase, which was the same as pure alumina. After the thermal treatment up to 1200 C, La-doped Al2O3 generated only one phase of θ-Al2O3 rather than two mixed phase of θ-Al2O3 and α-Al2O3 and the surface area could still maintain 101 m2/g with a keeping pore volume of 0.66 cm3/g. The excellent thermal stability was explained by the titration of strong Lewis acid sites of γ-Al2O 3 with the assistance of highly dispersed lanthanum species covering on alumina. Furthermore, the lanthanum modified mesoporous alumina was preliminarily employed as a stable support for Pd in the catalytic oxidation of C3H8. © 2013 The Chinese Society of Rare Earths.

Keyword:

calcinations; lanthanum; mesoporous alumina; rare earths; thermal stability

Community:

  • [ 1 ] [Jiang, L.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wang, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Wang, X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Luo, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Cao, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Rare Earths

ISSN: 1002-0721

Year: 2013

Issue: 11

Volume: 31

Page: 1081-1084

1 . 3 4 2

JCR@2013

5 . 2 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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