Ferrocenyl　derivatives　as　burning　rate　catalysts　for　hydroxyl-terminated　polybutadiene(HTPB)　have　been　used　widely.　Among　them,　binuclear　ferrocenyl　compounds　perform　much　better　due　to　good　thermal　stability,　low　volatility　and　migration　so　as　to　gradually　be　an　important　kind　of　burning　rate　catalyst.　Research　showed　that　N-heterocyclic　energetic　material　compared　to　traditional　ones　had　excellent　catalytic　effect　and　can　be　easily　controlled　through　changing　anion　or　cation.　Considering　performance　superposition　principle,　a　tetrazole　and　binuclear　ferrocenyl　should　be　combined　into　a　molecule　for　mixing　both　excellences.　In　order　to　reduce　volatility,　migration　and　energy　losses　of　such　catalysts,　groups　containg-N　can　be　introduced　to　enhance　molecule　polarity　and　strengthen　van　der　Waals　force　between　them　and　propellant,　which　are　in　favor　of　formation　of　hydrogen　bond　and　increase　of　viscoplastic　of　HTPB　within　kept　of　high　iron　content　of　catalyst　as　a　result　of　high　combustion　catalytic　performance.　This　paper　provides　a　multistep　procedure　for　the　preparation　of　5-(2,　2-diferrocenylpropane)-1H-tetrazole(4).　After　stepwise　biopolymer　and　Vilsmeier　formylation,　2,　2-diferrocenylpropane　carbaldehyde(1)　was　synthesized　from　ferrocene　with　moderate　yield,　and　then　compound　1　was　transformed　into　2,　2-diferrocenylpropane　carbaldehyde　oxime(2).　Dehydration　of　the　oxime　gave　2,　2-diferrocenylpropane　nitrile(3).　Finally,　compound　4　was　obtained　via　click　reaction([2+3]　cycloaddi-tion)　between　compound　3　and　sodium　azide.　Structures　of　the　target　compounds　were　characterized　by　1H　NMR,　FTIR　and　mass　spectrum.　Electrochemical　properties　of　the　target　compounds　were　investigated　by　cyclic　voltammetry　and　differential　pulse　voltammetry.　Relationship　between　electrochemical　behavior　of　multi-component　redox　and　structure　was　discussed.　Thermal　decomposition　characteristics　of　ammonium　perchlorate(AP)　with　5%(mass　fraction)　of　compound　3　or　4　were　investigated　by　differential　scanning　calorimetry(DSC)　and　thermogravimetry(TG)　analysis.　The　results　showed　that　the　final　exothermic　peak　temperature　of　AP　was　reduced　by　about　100°C　and　compounds　3　and　4　had　good　combustion　catalytic　characteristics　on　AP.