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Effects of antibacterial aging treatment on the corrosion resistance of copper-bearing duplex stainless steels were investigated by electrochemical methods. The film-cover method was used to test the antibacterial effect of the materials. The polarization curve test results show ε-Cu and other copper-rich phases become the weak point of the passive film on the surface of the duplex stainless steel, and the sites where the coarse copper-rich phases are precipitated from the matrix are apt to become pitting nucleation source. The proportion of coarse copper-rich phase increases, which makes pitting resistance of the materials worse. EIS test reveals that the presence of ε-Cu and other copper-rich phases in passive film reduces the overall potential and passive film resistance, decreasing the stability of passive film. DL-EPR tests show that ε-Cu and other copper-rich phases in grain boundary makes it take on anode characteristic in corrosion process, leading to selectively intergranular corrosion. Compared with austenite, the intergranular corrosion resistance of ferrite decreases seriously because the copper-rich phases are mainly precipitated from ferrite matrix. Antibacterial tests show that the microstructure and volume fraction of copper-rich phases are the key factors affecting the antibacterial properties of the materials. ε-Cu displays the best antibacterial effect, followed by metastable copper-rich phase, solid solution copper is the worst. The more ε-Cu phases are, the more antibacterial effect is. © Copyright.
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Acta Metallurgica Sinica
ISSN: 0412-1961
Year: 2012
Issue: 9
Volume: 48
Page: 1089-1096
0 . 6 1 2
JCR@2012
2 . 4 0 0
JCR@2023
JCR Journal Grade:2
CAS Journal Grade:4
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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