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author：

Li, J.-H. (Li, J.-H..) [1] | Li, M.-Z. (Li, M.-Z..) [2] | Miao, J. (Miao, J..) [3] | Wang, J.-B. (Wang, J.-B..) [4] | Shao, X.-S. (Shao, X.-S..) [5] | Zhang, Q.-Q. (Zhang, Q.-Q..) [6]

Indexed by：

Scopus

Abstract：

An　attempt　to　improve　hydrophilicity　and　anti-fouling　properties　of　PVDF　membranes,　a　novel　amphiphilic　zwitterionic　copolymer　poly(vinylidene　fluoride)-graft-poly(sulfobetaine　methacrylate)　(PVDF-g-PSBMA)　was　firstly　synthesized　by　atom　transfer　radical　polymerization　(ATRP)　and　used　as　amphiphilic　copolymer　additive　in　the　preparation　of　PVDF　membranes.　The　PVDF-g-PSBMA/PVDF　blend　membranes　were　prepared　by　immersion　precipitation　process.　Fourier　transform　infrared　attenuated　reflection　spectroscopy　(FTIR-ATR)　and　X-ray　photoelectronic　spectroscopy　(XPS)　measurements　confirmed　that　PSBMA　brushes　from　amphiphilic　additives　were　preferentially　segregated　to　membrane-coagulant　interface　during　membrane　formation.　The　morphology　of　membranes　was　characterized　by　scanning　electron　microscopy　(SEM).　Water　contact　angle　measurements　showed　that　the　surface　hydrophilicity　of　PVDF　membranes　was　improved　significantly　with　the　increasing　of　amphiphilic　copolymer　PVDF-g-PSBMA　in　cast　solution.　Protein　static　adsorption　experiment　and　dynamic　fouling　resistance　experiment　revealed　that　the　surface　enrichment　of　PSBMA　brush　endowed　PVDF　blend　membrane　great　improvement　of　surface　anti-fouling　ability.　©　2012　Elsevier　B.V.

Keyword：

Amphiphilic zwitterionic copolymer; Anti-fouling ability; Hydrophilicity; PVDF membrane

Community：

  • [ 1 ] [Li, J.-H.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 2 ] [Li, M.-Z.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 3 ] [Miao, J.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 4 ] [Wang, J.-B.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 5 ] [Shao, X.-S.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 6 ] [Zhang, Q.-Q.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China
  • [ 7 ] [Zhang, Q.-Q.]Institute of Biomedical Engineering, Chinese Academy of Medical Science, Peking Union Medical College, Tianjin 300192, China

Reprint 's Address：

  • [Li, J.-H.]Inst. of Biomedical and Pharmaceutical Technology and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350001, China

Email：


jhli_2005@163.com
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Source ：

Applied Surface Science

ISSN： 0169-4332

Year： 2012

Issue： 17

Volume： 258

Page： 6398-6405

2 . 1 1 2

JCR@2012

6 . 3 0 0

JCR@2023

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 161

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 4

Affiliated Colleges：

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