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author:

Yu, C.-L. (Yu, C.-L..) [1] | Cao, F.-F. (Cao, F.-F..) [2] | Shu, Q. (Shu, Q..) [3] | Bao, Y.-L. (Bao, Y.-L..) [4] | Xie, Z.-P. (Xie, Z.-P..) [5] | Yu, J.C. (Yu, J.C..) [6] | Yang, K. (Yang, K..) [7]

Indexed by:

Scopus PKU CSCD

Abstract:

A series of novel bismuth oxyhalide Ag/BiOX (X=Cl, Br, I) composite photocatalysts were synthesized by a solution-based photodeposited method at room temperature. The resulting products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) emission spectroscopy, UV-Vis diffuse reflectance spectroscopy (DRS), and N 2 physical adsorption. The photocatalytic activity of the samples was evaluated by photocatalytic degradation of acid orange II under visible light (420 nm<λ<660 nm) irradiation. Analysis by N 2 physical adsorption showed that deposition of Ag decreased the specific surface area of the catalyst. UV-Vis DRS analysis indicated that the presence of Ag could result in surface plasmon absorption, effectively increasing the visible light absorption ability of BiOCl and BiOBr. Furthermore, PL analysis indicated that Ag could effectively suppress the recombination of photogenerated electron (e-)-hole (h +) pairs of Ag/BiOX. Activity testing indicated that the deposition of an optimal amount of 1%-2% (w, mass fraction) Ag brought about 10, 13, and 2 fold increases in the photocatalytic activity of BiOCl, BiOBr, and BiOI, respectively. The high photocatalytic performance of the composite photocatalysts could be attributed to the strong visible light absorption, silver plasmon photocatalysis role and the recombination restraint of the e-/h+ pairs resulting from the presence of metal silver particles. © Editorial office of Acta Physico-Chimica Sinica.

Keyword:

Acid orange II; Bismuth oxyhalide; Photocatalysis; Promotion; Silver deposition; Visible light

Community:

  • [ 1 ] [Yu, C.-L.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China
  • [ 2 ] [Cao, F.-F.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China
  • [ 3 ] [Cao, F.-F.]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Shu, Q.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China
  • [ 5 ] [Bao, Y.-L.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China
  • [ 6 ] [Xie, Z.-P.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China
  • [ 7 ] [Yu, J.C.]Department of Chemistry, The Chinese University of Hong Kong, Hong Kong, China
  • [ 8 ] [Yang, K.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China

Reprint 's Address:

  • [Yu, C.-L.]School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China

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Source :

Acta Physico - Chimica Sinica

ISSN: 1000-6818

Year: 2012

Issue: 3

Volume: 28

Page: 647-653

0 . 8 6 9

JCR@2012

1 0 . 8 0 0

JCR@2023

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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