Synthesis and characterization of a new organically templated aluminophosphite with a chainlike structure - Details

author：

Xiang, Y. (Xiang, Y..) ^[1] | Zhang, L.-W. (Zhang, L.-W..) ^[2] | Chen, W.-H. (Chen, W.-H..) ^[3] | Chen, J.-Z. (Chen, J.-Z..) ^[4] | Zeng, Q.-X. (Zeng, Q.-X..) ^[5]

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Abstract：

A　new　aluminophosphite　(H4bape)0.5[Al(OH)(HPO　3)2]　has　been　synthesized　under　hydrothermal　conditions　and　its　structure　was　determined　by　single-crystal　X-ray　diffraction　(bape　=　N,N′-bis(2-aminopropyl)ethylenediamine).　This　compound　crystallizes　in　the　triclinic　system　with　the　space　group　P1̄　(No.　2),　a　=　6.919(2)　Å,　b　=　8.704(2)　Å,　c　=　9.786(2)　Å,　α　=　77.74(3)°,　β=　72.43(3)°,　γ　=　72.52(3)°,　V　=　531.08(2)　Å3,　Z　=　2.　The　structure　consists　of　distorted　octahedral　AlO6　and　pseudo　pyramidal　HPO3,　which　are　connected　by　vertex　oxygen　atoms　to　form　a　chainlike　framework　with　a　Al/P　ratio　of　1/2.　The　presence　of　ID　infinite　Al-O-Al　linkage　in　the　framework　is　noteworthy.　The　organic　templates　are　fully　protonated　and　interact　with　the　aluminophosphite　chains　through　extensive　hydrogen　bonds　to　form　a　3D　supramolecular　network.　©　2007　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA.

Keyword：

Aluminophosphite; Characterization; Crystal elucidation; Hydrothermal synthesis; Organic template

Community：

[ 1 ] [Xiang, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 2 ] [Zhang, L.-W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 3 ] [Chen, W.-H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 4 ] [Chen, J.-Z.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 5 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 6 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Xiang, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2007

Issue： 10

Volume： 633

Page： 1727-1730

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JCR@2023

JCR Journal Grade：3

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