The spectra and stabilities of alkoxyl-substituted phthalocyaninatometals. I. The effect of axial coordination abilities of the center metals on their stabilities in benzoyl peroxide - Details

author：

Lin, M.-J. (Lin, M.-J..) ^[1] | Yang, L. (Yang, L..) ^[2] | Wang, J.-D. (Wang, J.-D..) ^[3]

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Abstract：

The　stabilities　of　phthalocyaninatometals　are　reduced　seriously　by　the　substitution　of　bulky　alkoxyl　substituents.　In　the　toluene,　tetra-α-(2,2,4-trimethyl-3-pentoxy)phthalocyaninatometals　can　be　decomposed　by　the　benzoyl　peroxide,　and　the　order　of　decomposition　rate　sorted　with　the　center　metals　is　Fe　＞　Co　＞　Cu　＞　Ni　＞　Pd,　which　showed　a　consistency　with　the　axial　coordination　abilities　of　the　center　metals.　©　2007　Elsevier　B.V.　All　rights　reserved.

Keyword：

Decomposition; Phthalocyanine; Spectra

Community：

[ 1 ] [Lin, M.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 2 ] [Lin, M.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, 350002, China
[ 3 ] [Yang, L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 4 ] [Yang, L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, 350002, China
[ 5 ] [Wang, J.-D.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 6 ] [Wang, J.-D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, 350002, China

Reprint 's Address：

[Lin, M.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China

Email：

meijin_lin@fzu.edu.cn

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Source ：

Journal of Molecular Catalysis A: Chemical

ISSN： 1381-1169

Year： 2007

Issue： 1-2

Volume： 273

Page： 156-159

2 . 7 0 7

JCR@2007

5 . 0 0 8

JCR@2018

JCR Journal Grade：2

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