Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine - Details

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Abstract：

Two　new　supramolecular　compounds,　[Ag(4,4′-bipy)]n　[Ag(HBTC)]n　(1)　and　[Cu(H2BTC)(2,2′-bipy)]　(2)　(HBTC/H2BTC　=　1,2,4-benzenetricarboxylate,　4,4′-bipy/2,2′-bipy　=　4,4′/2,2′-bipyridine),　have　been　synthesized　and　characterized　by　elemental　analyses,　IR　spectra,　ultraviolet-visible　diffuse　reflection　integral　spectra　(UV-Vis　DRIS),　fluorescent　spectra,　thermogravimetric　analysis　and　single　crystal　X-ray　diffraction　analysis.　It　is　noteworthy　that　there　were　two　kinds　of　one-dimensional　stairs-chain　including　cationic　[Ag(4,4′-bipy)]n　chain　and　anionic　[Ag(HBTC)]n　chain　in　1.　Furthermore,　a　two-dimensional　double　layer　supramolecular　framework　was　constructed　through　coordination　bonds,　hydrogen　bonds,　π-π　stacking　interactions　and　Ag⋯O　weak　coordinative　interactions.　The　one-dimensional　supramolecular　chain　of　2　was　built　from　combining　mononuclear　[Cu(H2BTC)(2,2′-bipy)]　by　inter-　and　intra-molecular　hydrogen　bonding　interactions.　Additionally,　the　two　complexes　exhibit　intense　blue　or　olivine　luminescence　at　room　temperature.　©　2007　Elsevier　B.V.　All　rights　reserved.

Keyword：

Copper(I); Hydrogen bonds; Mixed ligands; Silver; Supramolecular framework

Community：

[ 1 ] [Zhang, S.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Zhang, S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Wang, Z.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Wang, Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Zhang, H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Zhang, H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 7 ] [Cao, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 8 ] [Cao, Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 9 ] [Sun, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 10 ] [Sun, Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 11 ] [Chen, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 12 ] [Chen, Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 13 ] [Huang, C.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 14 ] [Huang, C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 15 ] [Yu, X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 16 ] [Yu, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Zhang, H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

zhanghh1840@hotmail.com

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Source ：

Inorganica Chimica Acta

ISSN： 0020-1693

Year： 2007

Issue： 8

Volume： 360

Page： 2704-2710

1 . 7 1 3

JCR@2007

2 . 7 0 0

JCR@2023

JCR Journal Grade：2

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WoS CC Cited Count：

SCOPUS Cited Count： 26

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

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